how an o-ring functions \ physical properties of o-ring compounds \ types of seals \ general design and gland dimensions \ standard o-ring sizes and dimensions \ compound information  

Basic O-Ring Elastomers and their Characteristics

AFLAS* (TFE Propylene)

Trade Name:
     *Above...............................................................................3M

This recently introduced material is unique due to its resistance to petroleum products, steam, phosphate esters and brake fluids. In some respects, it exhibits media compatibility properties similar to ethylene propylene and fluorocarbon. It has fair resistance to brake-fluids and phosphate esters while exhibiting good resistance to petroleum oils. This material is finding interest for seal applications requiring petroleum resistance, steam and ammine resistance such as those applications encountered in the petroleum industry. Additional interest is being generated in applications requiring petroleum and brake fluid resistance or petroleum and phosphate ester resistance. The temperature service range for this material is -20°F to +400°F.

Applications:
     Petroleum fluids & steam
     Petroleum fluids & ammines
     Petroleum fluids & brake fluids
     Petroleum fluids & phosphate ester

ETHYLENE PROPYLENE (EPM, EPDM)

(Ethylene Propylene Copolymer)

Trade Names:
   Nordel . . . . . . . . . . . . . DuPont Dow
   Vistalon . . . . . . . . . . . . Exxon Chemical
   Epsyn . . . . . . . . . . . . . .Copolymer Rubber
   Royalene . . . . . . . . . . . Uniroyal

This material was introduced in 1961 and found broad acceptance in application requiring excellent resistance to Skydrol and other phosphate ester fluids at higher temperatures. In addition, compounds of this material exhibit excellent resistance to automotive brake fluids and steam.

The temperature service range for these compounds is -65°F to +300°F.
 

Applications:

Automotive Brake Fluids
Water/Hot water 
Steam (to 400°F)
Silicone Fluids
Some Acids (Dilute)
Ketones
Phosphate Esters such as Skydrol

 

FLUOROCARBON (FKM)

(Vinylidene fluoride-hexafluoropropylene)

Trade Names:
   Fluorel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3M
   Viton . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .  DuPont-Dow

Compounds of these polymers exhibit excellent resistance to petroleum products, low compression set and high temperature resistance. The low temperature capability is somewhat restricted, however, in some case the flow temperature sealing capability may be increased by specific design parameters. These materials meet the stringent requirements of Military Specifications Mil-R83248 and Aerospace Specifications AMS 7278, AMS 7279, and AMS 7280. They are especially good for hard vacuum service and low gas permeability. The normal temperature service range in fluorocarbon is -20°F to +400°F / + 450°F.
 

Media Compatibility
Petroleum Fluids
Diester Lubricants
Silicone Fluids
Halogenated hydrocarbons
   (Above 212°F)
Some Acids
Selected Fluids

Non-Compatible:
Skydrol
Ammines
Ketones
Hot Water
Steam
Brake Fluids

FLUOROSILICONE (FVMQ)

Trade Names:
   LS  . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dow
   FSE  . . . . . . . . . . . . . . . . . . . . . . . . . . . .GE

These polymers exhibit good low/high temperature resistance with excellent resistance to petroleum oils and fuels. They are used in aerospace applications for fuel systems and systems requiring resistance to diester base lubricants to 350°F. Due to the limited strength and abrasion resistance of these materials, they are generally recommended for static applications only. The sealing temperature service range is -80°F to +350/400°F.
 

Applications
Petroleum oils & fuels
Dry Heat/Oil

Non-Compatible
Phosphate esters
Dynamic applications

 

NEOPRENE (CR) CHLOROPRENE

Trade Names:
Bayprene  . . . . . . . . . . . . .  Mobay
Butchlor . . . . . . . . . . . . . . . Ditsugil

This was the earliest of the volume American synthetic rubbers. Compounds from neoprene exhibit fair oil resistance, good ozone and weather resistance. Due to the excellent resistance to refrigerants such as Freon, neoprene compounds are used in refrigeration systems. The sealing temperature service range for these compounds is -65°F to +250/300°F.
 

Applications
Refrigerants (Freons)
High Aniline Point Oils
Weather and Ozone
Ammonia Gas
Silicate Esters

Non-Compatible
Phosphate esters
Ketones
Brake Fluids

 

NITRILE (NBR or Buna N)

(Acrylonitrile-Butadiene Copolymers)

Trade Names:
Chemigum  . . . . . . . . . . . . . . Goodyear
Hycar  . . . . . . . . . . . . . . . . . .Zeon Chemical
Krynac  . . . . . . . . . . . . . . . . .Polysar
Ny Syn  . . . . . . . . . . . . . . . . .Copolymer
Paracril  . . . . . . . . . . . . . . . . .Uniroyal
Perbunan  . . . . . . . . . . . . . . . Mobay

Compounds of these polymers are the backbone of the O-Ring line. Polymers vary from 18 percent to 50 percent acrylonitrile content. Resistance to petroleum products increases as acrylonitrile increases; conversely, low temperature flexibility decreases. Government specifications require low acrylonitrile.

Nitrile Compounds can exhibit excellent compression set, tear and abrasion resistance. Unless especially compounded, they do not have good resistance to ozone, sunlight, or weather. They should not be stored near motors or other ozone generating electrical equipment. They should be kept from direct sunlight. Compounds from nitrile rubber can exhibit a temperature range of -65°F to +300°F, although no one formulation may exhibit the total range.
 

Media Compatibility
Petroleum Fluids
Water (212°F)
Silicone fluids
Ethylene Glycol
General Purpose

Non-Compatible
Phosphate esters
Ketone
Brake fluids
Strong Acids
Ozone or Weathering

 

HIGHLY SATURATED NITRILE (HSN)

Trade Names:
Therban . . . . . . . . . . . . . . Mobay
Zetpol  . . . . . . . . . . . . . . . Zeon Chemical
Tornac  . . . . . . . . . . . . . .  Polysar

This material is a highly saturated nitrile.

Therban exhibits excellent abrasion, compression set, tensile, and tear properties. Unlike standard nitriles, it exhibits resistance to ozone, sunlight, and other atmospheric conditions. This material also exhibits vastly improved resistance to heat aging in the 300°F range and, for short periods, up to 350°F. Presently available material exhibits a low temperature range to -40°F.
 

Applications
Petroleum Fluids
Water
Silicone Fluids
Ethylene Glycol
Ozone & Weathering
Amines
Automotive Freon "R134A"

Non-Compatible
Phosphate Esters
Ketones
Brake Fluids
Strong Acids
Keronsene
Methanol/Ethanol Blends

SILICONE (VMQ)

Trade Names:
Silastic  . . . . . . . . . . . . . . .Dow
None  . . . . . . . . . . . . . . . .General Electric
None  . . . . . . . . . . . . . . . .Stauffer-Wacker
None . . . . . . . . . . . . . . . . Union Carbide

Silicones are noted for their excellent heat resistance, and are utilized in applications which expose seals to high temperature dry heat. They are not recommended for dynamic applications due to their relatively poor tensile and tear strength. They exhibit the best low temperature flexibility of all elastomers and can be used in static applications to -150°F. Silicones should be considered to be non-petroleum resistant, but can be used in specific high aniline point petroleum oils. The temperature service range for silicone compounds is -80°F to 450°F (All silicone formulations do not exhibit the capability of this entire range).
 

Applications
High temperature (Dry heat)
Low Temperature
High Analine point oil

Non-Compatible
Most petroleum oils
Ketones
Dynamic applications